"MTV Unplugged in Athens" includes a selection of the Scorpions' greatest hits, reimagined in an unplugged format. Some of the notable songs performed on the album include "Rock You Like a Hurricane," "Wind of Change," "Still Loving You," and "Send Me an Angel." The band experimented with different arrangements, incorporating orchestral elements and acoustic instruments to create a fresh take on their classic rock sound.
The album was well-received by fans and critics alike, showcasing the band's versatility and ability to adapt their music to different styles. It served as a testament to the Scorpions' enduring popularity and their ability to captivate audiences in both electric and acoustic settings.